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Pressure Cooker

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Pressure Cooker

Am I right to be afraid of pressure cookers? What's the worst thing that can happen if you misuse a pressure cooker in an ordinary kitchen?

—Delphine Lourtau

The worstthing?

Pressure cookers are dangerous.

They can explode, in a sense, but not as violently as you might fear (or hope). The pressure inside a consumer cooker doesn’t go above about two atmospheres—about the pressure inside a can of soda. Those levels can be dangerous, but they’re generally not high enough to cause the metal to violently rupture.

So what makes a pressure cooker dangerous?

Imagine a world where Pepsi is scalding hot. Now imagine that someone shakes up a can of Pepsi and sets it in front of you.

That’s the real threat from a pressure cooker: If the seal fails (or the lid is opened too early), it can spray scalding stew in all directions.

But it’s not really an explosion.

The blast couldn’t even fling the lid very far. If you mounted a rifle-style barrel on a pressure cooker, even in ideal circumstances it wouldn’t be able to fire the lid much faster than you could throw it. Any potato cannon (especially this one) could do better.

Of course, the question wasn’t about whether a pressure cooker is likely to explode. It was about what the worst thing that could happen was.

If you disable the safety valve, there are plenty of ways to produce much more dangerous pressures. You could completely fill it with water and heat it, fill it with Drano Draino and aluminum foil, or just pump in air from a compressor.

The result would depend on your pressure cooker. Chances are it would start to leak. If it didn’t, and it somehow stayed together up a few hundred atmospheres (pressures typical of scuba tank), when it finally rupturedit could easily kill you.

Even so, that’s far from the worstthing you could do with a pressure cooker.

Frankly, there are so many options it would be impossible to survey them all. But for my money, one of the most horrifying things you could do is this:

(Note: Nevertry this, for reasons which will become obvious in a moment.)

Fill the cooker with oxygen up to 5 PSI, then pump in fluorine until it starts escaping through the safety valve. Put the vessel over an open flame until it reaches 700°C (That’s °C, not °F. Yes, this will probably set off the smoke alarm.) Now, pump the hot gas over a liquid-oxygen-cooled stainless steel surface.

The procedure here is a little tricky, but if you do things right, the gas will condense into dioxygen difluoride(O2F2).

And that stuff is awful.

Ray Bradbury taught usthat paper burns when exposed to oxygen at temperatures above 451°F. Dioxygen difluoride is so volatile that it makes almost any organic substance ignite and explode at any temperature hotter than 300°F below zero.It can literally make icecatch fire.

In an article about O2F2, Chemistry blogger Derek Lowe (of the excellent In The Pipeline) used phrases like “violently hideous”, “deeply alarming”, and “chemicals that I never hope to encounter”. Another articlerefers to fluorine as “the gas of Lucifer”, and lists chemists who were poisoned or blown up while attempting to work with it.

If your house is heated by natural gas, and it happens to contain hydrogen sulfide, you could pipe some of it into your container of O2F2. In addition to a massive explosion, this will alsoproduce a cloud of hydrogen fluoride gas. Hydrogen fluoride can dissolve human tissue on contact, starting with your lungs and corneas.

As Lowe points out, the chemistry of this kind of reaction (O2F2 and sulfides) is largely unexplored.

Which gives us an answer to our question. What’s the worst thing that can happen in a pressure cooker?


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3150 days ago
Were lost socks go
3161 days ago
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15 public comments
3149 days ago
I only just caught this article today. Rather surprising coincidence for the choice of subjects.
3160 days ago
Good one!
3162 days ago
Whats rhe worst that can happen? SCIENCE, Baby!
3162 days ago
XKCD's What If? Pressure Cooker
Denver, CO
3162 days ago
science indeed! This is so math
Space City, USA
3162 days ago
From the don't try this at home department....
3162 days ago
I love what-if. Also, I am never buying a pressure cooker
3162 days ago
Randall Munroe wins all the internets. All of them.
Yonkers, NY
3162 days ago
"What's the worst thing that can happen in a pressure cooker?

Wake Forest, North Carolina
3163 days ago
I love the shout-out.
3156 days ago
This was most interesting to be because I learned that he adds alt-text to the comics in these articles, too!!!
3163 days ago
Epic ending.
3163 days ago
Have you ever heard of the 'gas of lucifer'? Then read this from What if? #sciencewin